Public Lab Research note


Preparing a DVD-R to act as a diffraction grating

by MrBumper | January 11, 2015 20:22 | 5,357 views | 14 comments | #11515 | 5,357 views | 14 comments | #11515 11 Jan 20:22

Read more: i.publiclab.org/n/11515


MrBumper was awarded the Basic Barnstar by warren for their work in this research note.


Main image - A segment of a DVD-R bottom layer with the photo-reactive dye removed

See also - http://publiclab.org/n/11552 Does leaving the dye on a DVD-R grating make any difference?

All DVD-Rs are made with two layers of moulded polycarbonate about 0.58mm thick, glued together. There is a guide groove for the burning laser moulded into the upper (inside) surface of the lower layer (the 'label' side being the top side of the DVD-R). This spiral guide groove has a sufficiently fine and regular pitch of 0.74 microns, to act as a diffraction grating. The aim of processing a DVD-R to convert it into a usable transmissive diffraction grating for a spectrometer is to end up with an optically transparent piece of the lower polycarbonate layer with the spiral groove moulded into one side. The DVD-R or any diffraction film must be handled very carefully (use rubber gloves) to avoid scratches, dirt and finger oils contaminating the optical surface.

The process starts with splitting the two polycarbonate layers apart. DVD-R splitting seems best done by first separating the entire disc into two halves, rather than cutting out a segment and splitting that. CDs and DVDs are injection moulded from polycarbonate and in theory, if the temperature of the liquid plastic and the mould are properly controlled, the moulded end product should be pretty tough and shatter resistant. In practice this is often not the case because the manufacturers don't control temperatures that carefully and don't reject product with high internal cooling stresses that are produced when the moulding machines are run up or down for production. I found for example that trying to cut up a DVD-R before splitting it resulted in a lot of shattering and cracking, although that should not happen on a properly made DVD.

A sharp craft knife can be applied to the edge and wiggled (very carefully) until it gains purchase between the two layers and starts them peeling apart. Once separation is started it can be completed by gently prising at the edges of the discs with the fingers. The aim is to get the lower part of the disc to peel away with as little of the aluminium left on it as possible, but the process is hit and miss. Once split like this it is relatively easy, using a pair of stout shears or scissors, to cut the plastic up into a suitably sized rectangle for use in a spectrometer.

The problem I found with the initial split is that I tended to end up with a lot of aluminium and purple tinted dye on the bottom half of the disc. I tried to remove the dye by soaking a piece of the DVD-R in a fairly strong household cleaner (Cillit Bang - which contains Sulfamic and Phosphoric acid and some detergent) designed to remove limescale.

NOTE - Further experiments show that the dye is easily soluble in plain water. Just soak a portion of the lower layer of the DVD-R in warm water (adding a little liquid soap helps) and, after only ten seconds or so gently moving the fragment back and forth, the dye starts to dissolve and wash away. Use purified distilled water if you are worried about contaminating the surface with minerals from the water.

The dye dissolves easily, but any aluminium silvering left on the bottom disc is quite hard to shift. On my first attempt I ended up with a clear piece of plastic that did not diffract, I must have used the wrong layer of the DVD-R (I have a big stack of cheap DVD-Rs that have no 'label' surface – the top looks much like the bottom). I have since repeated the experiment, and with the dye removed, I have a clear section of polycarbonate that still diffracts. The colour filtering due to the dye must affect the response of a finished spectrometer if the dye is left in place. In comparison holographic film grating, or a properly processed piece of DVD-R material are colourless.

If you get stuck with a lot of aluminium left on the bottom half, then getting rid of it is harder than dissolving the dye. I used some drain cleaner granules (basically caustic soda a.k.a. lye or sodium hydroxide) mixed with water. After a good long soak the aluminium flaked off in small pieces. Be very careful with caustic soda, it can cause nasty burns.

If anyone comes up with better solvents or methods for cleaning a DVD-R of aluminium and dye please let me know. I have seen it suggested that these coatings, or at least the aluminium, can be peeled off by rubbing down sections of adhesive packing tape and then pulling it off, but I haven't been able to make this work.

BTW – Providing you leave a part of the centre of the DVD-R in place on any piece you cut, you can tell which surface the grooves are on. Most DVD-Rs have a moulded ring or circular bump near the centre hole. The bump is on the outside surface and the grooves are on the inside.

As it says in various places on the Public Lab site, the grooves in the DVD-R surface must be oriented as close to parallel with the spectrometer slit as possible. I found that it was relatively easy to cut a geometric segment or pie slice out of the DVD-R material using the edge and the centre hole as reference. However judging the geometry correctly to trim that slice down to a rectangle and maintain the orientation of the grooves was much harder.

NOTE - The kit for the Public Lab Spectrometer 3.0 now includes a small binder, or butterfly, clip to clamp the DVD-R diffraction grating to the angled grating support. This allows for easy replacement or adjustment of the grating. Gratings with and without dye can easily be tried out and If the output from the web cam shows that the grating is not parallel to the slit, the grating can often be nudged into the correct orientation without removing the clip.

DVD-Rsplitandholofilm.png

Image 2 - Bottom half of a split DVD-R (supplied with the PL kit). The purple / blue tint from the photo sensitive dye is clearly visible and the distribution of the dye remaining on the surface seems to vary a lot. A rectangle of the 1,000 lpmm holographic film can be seen for comparison, lying in the cut away section of the DVD-R. It appears to be colourless.


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14 Comments

This is so clearly and thoroughly explained! How about linking to it from the dsk and foldable spectrometer instructions pages?

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This is great information. I don't know of any comparisons between DVD-R and DVD+R Do you think either will work for making a grating?

Some DVDs are double layer. The groove spacing should be the same, but they might be harder to split apart cleanly. Does anybody have any experience comparing single and double layer DVDs?

Below are some diagrams that helped me understand what we are doing. The lowermost layer (polycarbonate) is the part we need for a grating. The second layer from the bottom is the dye (recording layer) which must be the purplish stuff that has to be removed. The "reflective layer," or "Metal layer," or "Metal reflector" also has to be peeled away completely. The first image is a single layer DVD, the second is a double-sided DVD, and the third is a double layer DVD.

cdr_cross_section_1.jpg

DVD-R-Cross-Sectionc.jpg

doublelayer1.gif

Image sources: http://www.riverproaudio.co.uk/Itemdesc.asp?ic=5060158310661 http://www.dvdservices.org/press/doublelayer.htm http://www.hughsnews.ca/wp-content/uploads/2011/05/DVD-R-Cross-Section-474x1024.jpg

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this lead to a massive thread on the mailing list: https://groups.google.com/forum/#!topic/plots-spectrometry/zxkwRR7D4ls

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As far as I know the guide groove on a DVD+R would be indistinguishable from that on DVD-R as far as using it for a diffraction grating is concerned. All these disks, both double and single layer are constructed with two polycarboante layers. In the dual layer disks the upper disk has a dye layer and is used for recording, in the single it doesn't and isn't. I think they should split just the same.

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In regards to your comment "grooves in the DVD-R surface must be oriented as close to parallel with the spectrometer slit as possible," in the past I've kept the DVD-R in wedge form, not cutting a rectangle. That way you can line up the bottom of the DVD-R curve with the bottom of the spec. My thought is this helps keeps the grooves oriented.

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I just tried this out-- I didn't find warm water alone effective, nor did I find just soaking in soapy water enough to remove the dye.

I found that soapy warm water would only take a bit of the dye off at a time. The best way I found was to alternate a quick rinse in soapy water with a quick rinse in warm water. 10x back and forth gave me a nice, clear DVD

IMG_20150204_155315-ed.png

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Matthew - I found that static soaking helps soften the dye. But then the dissolved dye just sits in solution above the surface of the DVD-R fragment. Gentle agitation helps to move the dissolved dye away from the surface and allows more to dissolve. It does take a while. Placing the fragments on top of a clean white sheet of paper or paper towel, as you did, helps to judge if the dye is really gone. If not - rinse - repeat. Or you can get ugly on it and use the industrial strength limescale removing cleaner (cold) as I did originally. And I guess solubility may depend on the exact dye formulation / brand of DVD-R used.

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Ethanol remove immediately organic dye and evaporates in few seconds.

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confirmed. Denatured alcohol pulled it off and dried without residue. That was really fast--it makes me wonder if we should use this method to make prepared gratings for the kits.

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Yo sumergí el el dvd en ácido clorhídrico diluido, del que se emplea en limpieza sanitaria, y se eliminaron los residuos de aluminio, no daña al policarbonato. no hablo ingles disculpen.

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Translation:

I submerged the DVD in diluted hydrochloric acid, of the kind used in sanitary cleaning, and it eliminated the aluminum residue, and did not damage the polycarbonate. I don't speak English, sorry.

Gracias Edilberto!

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stick the plastic tape onto the large aluminium part, tease off the tape and at the same time the aluminium part will be tease off at the same time Repeat this part for several time! After that, rinse with ethanol !

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I used Everclear 180 proof (ethanol) and the point of a sharp Exacto knife to both tease the layers apart and remove all the dye. The ethanol seemed to assist the separation of the plastic layers significantly (Vodka worked also but was quite a bit slower.) Then to eliminate the aluminum I just added a few drops of dish detergent or Prell shampoo, and rubbed between my fingers, The detergent just lifted the aluminum off and flaked it away. Result was complete use of the whole DVD-R for making multiple gratings. I also constructed a prototype spectrometer using the front surface reflector grating from the aluminum itself. Seemed to work even better in the UV than the trasmission grating approach.

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Simply use some nailpolish remover (from your sister's cabinet :P) to remove all the dye within seconds. You can make reflective as well as clear transmission grating from DVD. Cheers !

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